Sizing combined gas for internal combustion engines: why PEM and alkaline aren't interchangeable.
Electrolytically-generated hydrogen and oxygen — oxyhydrogen — has a long, proven track record in combustion enhancement. Traditional alkaline (Brown's Gas) electrolysis is a well-established, effective technology, and at industrial scale — large boilers and thermal plant — it's genuinely well suited to the task. That's not in question here.
This article is about a narrower, more practical issue: how much combined gas an internal combustion engine actually needs, and why the volume specification for that application differs depending on the electrolysis technology producing the gas.
Can an alkaline gas-volume benchmark be used to size a PEM system?
No. How much combined gas an internal combustion engine needs for a given effect depends on the purity of the gas delivered as well as on displacement. A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean PEM stream at 99.991% purity does not. A litres-per-hour benchmark established on an alkaline system is therefore not a reliable guide for sizing a PEM system on the same engine — which is why the HydroHub™ range is specified against engine capacity in litres of displacement.
- Alkaline (Brown's Gas) electrolysis is effective and well suited to industrial-scale plant
- PEM produces the same H₂/O₂ stream through a solid polymer membrane, not a liquid bath
- No liquid caustic electrolyte means no electrolyte mist in the gas stream
- PEM gas purity: 99.991%
- HydroHub™ units are specified by engine displacement, not by a carried-over gas volume
- Confirm the unit for a specific engine and duty cycle with a field trial
- PEM gas purity
- 99.991%
- PEM electrolyte
- Solid polymer membrane
- Alkaline electrolyte
- Liquid KOH bath
- Sizing basis
- Engine displacement (L)
Two different volume pictures.
Alkaline electrolysis produces oxyhydrogen using a liquid potassium hydroxide (KOH) electrolyte bath. It scales well to high-volume industrial applications, and decades of use — including our own on-road testing — have established practical volume benchmarks for specific engines and flow rates in that context.
PEM (proton exchange membrane) electrolysis produces the same kind of combined H₂/O₂ stream, but through a different process — a solid polymer membrane rather than a liquid electrolyte bath. One direct consequence: no liquid caustic electrolyte means no electrolyte mist carried into the gas stream, and a resulting gas purity of 99.991%.
| Criterion | PEM | Alkaline (Brown's Gas) |
|---|---|---|
| Electrolyte | Solid polymer membrane | Liquid potassium hydroxide (KOH) bath |
| Gas purity | 99.991% — no electrolyte mist carry-over | Electrolyte mist carry-over is a known handling issue |
| Scale it suits best | Mobile and on-engine applications | High-volume industrial plant and large boilers |
| Sizing basis used here | Engine capacity (litres of displacement) | Established gas-volume / flow-rate benchmarks |
| Effective active gas per unit volume | Full — the stream is the product | Reduced by whatever is carried with the stream |
| Track record | Current HydroHub range | Decades of use, including our own on-road testing |
Purity changes the effective volume.
For internal combustion engines specifically, the question that matters is: how much combined gas does the engine actually need for a given effect? That answer isn't just a function of engine displacement — it also depends on the purity of the gas being delivered.
A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean, high-purity PEM stream doesn't. That means a volume benchmark established on an alkaline system isn't a reliable guide for sizing a PEM system for the same engine — treating the two as directly interchangeable on a litres-per-hour basis risks over- or under-sizing the unit for the application.
This is why our PEM product range is specified against engine capacity (litres of displacement) rather than against a fixed gas-volume benchmark carried over from alkaline systems — the sizing logic has to account for the technology actually producing the gas.
| HydroHub™ A-450 | HydroHub™ A-675 | HydroHub™ A-900 | HydroHub™ H-Power | HydroHub™ DH-Power |
|---|---|---|---|---|
| 1.0 – 1.8 L | 2.0 – 2.5 L | 2.7 – 7.0 L | Up to 7.0 L | Up to 16.0 L |
Full specifications side by side on compare systems.
Measure it on the actual equipment.
As with any combustion-enhancement application, the most reliable way to confirm the right unit for a specific engine and duty cycle is a field trial — measuring real results on the actual equipment, rather than assuming a figure from a different technology carries across unchanged.
- · Fleet trial programme — baseline, controlled fitment and reporting.
- · Installation guide — step-by-step fitting guidance.
- · PEM vs alkaline — servicing, handling and cost comparison.
- · PEM electrolysis — stack, water treatment and control detail.
No projected, typical or expected fuel-saving figure is published. Actual results vary materially with engine condition, duty cycle, load profile, fuel quality, installation and operating conditions. A controlled field evaluation on your own equipment, with baseline data captured before installation, is required before any commercial projection.
Questions.
Is alkaline electrolysis a bad technology?
- No. Traditional alkaline (Brown's Gas) electrolysis is a well-established, effective technology with a long track record in combustion enhancement, and at industrial scale — large boilers and thermal plant — it is genuinely well suited to the task. That is not in question. The narrower point on this page is about how the volume specification for an internal combustion engine differs depending on which technology produces the gas.
Why can't I use an alkaline litres-per-hour figure to size a PEM unit?
- Because how much combined gas an engine needs for a given effect is not purely a function of displacement — it also depends on the purity of the gas delivered. A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean, high-purity PEM stream does not. Treating the two as directly interchangeable on a litres-per-hour basis risks over- or under-sizing the unit for the application.
What purity does PEM deliver?
- 99.991%. There is no liquid caustic electrolyte in a PEM cell, so there is no electrolyte mist to be carried into the gas stream.
So how is the HydroHub™ range specified?
- Against engine capacity — litres of displacement — rather than against a fixed gas-volume benchmark carried over from alkaline systems. The sizing logic has to account for the technology actually producing the gas.
How do I confirm the right unit for my engine?
- A field trial. As with any combustion-enhancement application, the most reliable confirmation is measuring real results on the actual equipment and duty cycle, rather than assuming a figure from a different technology carries across unchanged.
Where sizing decisions get made.
Displacement bands, duty cycle and trial protocol per application.
Mining fleets →
Haul trucks, articulated dumpers, production dozers, loaders, drill rigs and camp gensets. Dust, pit heat and remote servicing decide as much as displacement does, and carted fuel changes what a percentage is worth.
Marine →
Workboats, charter and dive vessels, ferries and ship's service gensets. Nothing is stored aboard — gas is made on demand — which is normally a surveyor's first question.
Agriculture →
Tractors, headers, sprayers, farm trucks and irrigation pump sets. Seasonal idle periods, on-farm water quality and distance from a dealer shape the specification.
Generator sets →
Stationary diesel gensets on continuous and prime duty from 100–500 kVA — remote camps, telecom sites and standby plant fed from the set's own starting battery.
All applications — the full vertical index →·Partner program →
Continue reading.
Hydrogen combustion enhancement
What it is, how PEM gas reaches the cylinder, and what it does not do.
Engine performance improvement
Flame speed, burn completeness and load response on diesel engines.
Fuel efficiency
How to baseline and measure litres per 100 km or litres per hour.
Emissions reduction
Soot, particulate and unburnt-fuel behaviour, and how to test it.
Visible smoke reduction
Smoke opacity findings per study, with the NOx trade-off disclosed.
Remote-site fuel logistics cost
Landed cost versus pump price, and why the same percentage moves more money.
Generator-set classes
Camp, prime, standby, rental, telecom, irrigation and ship's service sets compared.
Idle & part-load duty cycles
Reefers, camp gensets and high-idle plant — where the literature reports most room.
Hydrogen with biodiesel blends
Per-study findings for hydrogen enrichment on biodiesel, NOx disclosed.
Installation guide
Nine-step fitting sequence: mounting, wiring, gas line, commissioning.
Safety & compliance
On-demand gas, no storage, alarms, shutdowns and reversibility.
Troubleshooting
Alarms, low gas output, water quality and no-start diagnostics.
Case studies & field results
Published operator data and trial methodology.
Compare PEM systems
A-450 to DH-Power side by side: displacement, output, current draw.
Does it actually work? Evidence review
The published literature, the FTC/EPA history and the ACL context.
How it works
Gas path and established physics, explained with diagrams.
PEM vs alkaline
Membrane on water versus caustic KOH: servicing, purity, cost.
Four hydrogen technologies
Enhancement vs H2ICE vs fuel cell vs chemical generation.
Compared with Hydrogen Fuel Systems
Honest comparison with the Perth-based Gen alkaline range.
Compared with H2i Technology
Hardware, pricing and evidence transparency versus the Victorian supplier.
Compared with dynaCERT HydraGEN
PEM versus alkaline, published price versus dealer quote, Verra versus ACCU.
Compared with HYDI
The South Australian manufacturer: UniSA testing, field history and quote path.
AU installation, warranty & safety
VSB 14 and VSB 6, ACL guarantees and documentation to keep.
Mining fleets
Haul trucks, dozers, drill rigs and site gensets: unit selection and dust.
Marine
Workboats, charter, fishing and ship's service gensets — no gas stored aboard.
Agriculture
Tractors, headers, pump sets and farm trucks across seasonal duty.
FAQ
Answers on fitment, water, warranty, freight and duty cycles.